Certainly! TDD works for any type of software project or products. TDD isn't meant just for new products or projects; it is also proven to be more effective with complex legacy projects or products. In a maintenance project, the vast majority of the time one has to fix defects and very rarely one has to support a new feature. Even in such legacy code, one can follow TDD while fixing defects. 

As a developer, you would readily agree with me that once you are able to reproduce the issue, almost half of the problem can be considered fixed from the developer's point of view. Hence, you can start with a test case that reproduces the issue and then debug and fix the issue. When you fix the issue, the test case will start passing; now it's time to think of another possible test case that may reproduce the same defect and repeat the process.